Search for: All records

Abstract The role of ocean dynamics in Atlantic climate variability and predictability is often studied through the lens of sea surface temperature (SST). Unlike SST, sea surface salinity (SSS) is not directly damped by surface fluxes, and its low-frequency variability responds primarily to oceanic processes. This study investigates the drivers of SSS variability using a stochastic model hierarchy to disentangle oceanic and atmospheric contributions to Atlantic climate variability, in particular, the role of local vertical processes. Representation of SST and SSS persistence and variance is especially improved by the introduction of damping of anomalies below the mixed layer, though SSS anomalies remain too persistent. The effect of SST–evaporation feedback on SSS is comparatively smaller except in regions with strong SST–SSS correlation. Despite the lack of representation of geostrophic advection, the stochastic model successfully reproduces spatial patterns of recurring SST/SSS anomalies in the Community Earth System Model 1 (CESM1) Large Ensemble at monthly to interannual time scales. At multidecadal time scales, the stochastic model is unable to simulate the amplitude of SST/SSS variability, but their spatial patterns are broadly reproduced, suggesting that direct atmospheric forcing and local vertical processes are important for capturing these features. Further analysis of the processes missing from the stochastic model suggests that the lack of geostrophic advection is largely responsible for too persistent SSS in the stochastic model, while the lack of interannual mixed-layer depth variability explains the underestimated persistence and variance in some regions for both SST and SSS. 

Abstract Understanding internal variability of the climate system is critical when isolating internal and anthropogenically forced signals. Here, we investigate the modes of Atlantic Meridional Overturning Circulation (AMOC) variability using perturbation experiments with the Institut Pierre‐Simon Laplace's (IPSL) coupled model and compare them to Coupled Model Intercomparison Project Phase 6 (CMIP6) pre‐industrial control simulations. We identify two characteristic modes of variability—decadal‐to‐multidecadal (DMD_var) and centennial (CEN_var). The former is driven largely by temperature anomalies in the subpolar North Atlantic, while the latter is driven by salinity in the western subpolar North Atlantic. The amplitude of each mode scales linearly with the meanAMOCstrength in the IPSL experiments. TheDMD_varamplitude correlates well with theAMOCmean strength across CMIP6 models, while theCEN_varmode does not. These findings suggest that the strength ofDMD_vardepends robustly on the North Atlantic mean state, while theCEN_varmode may be model‐dependent. 

Abstract Vanadium Dioxide (VO₂) is a material that exhibits a phase transition from an insulating state to a metallic state at ≈68 °C. During a temperature cycle consisting of warming followed by cooling, the resistivity of VO₂changes by several orders of magnitude over the course of the hysteresis loop. Using a focused laser beam (λ = 532 nm), it is shown that it is possible to optically generate micron‐sized metallic patterns within the insulating phase of a VO₂planar junction which can be used to tune, on demand, the resistance of the VO₂junction. A resistor network simulation is used to characterize the resulting resistance drops in the devices. These patterns persist while the base temperature is held constant within the hysteretic region while being easily removed totally by simply lowering the base temperature. Surprisingly, it is also observed that the pattern can be partially erased using an atomic force microscope (AFM) tip on the submicron scale. This erasing process can be qualitatively explained by the temperature difference between the VO₂surface and the tip which acts as a local cooler. This optical and AFM resistive fine‐tuning offers the possibility of creating controllable synaptic weights between room‐temperature VO₂neuristors. 

Abstract The models that participated in the Coupled Model Intercomparison Project (CMIP) exhibit large biases in Arctic sea ice climatology that seem related to biases in seasonal atmospheric and oceanic circulations. Using historical runs of 34 CMIP6 models from 1979 to 2014, we investigate the links between the climatological sea ice concentration (SIC) biases in September and atmospheric and oceanic model climatologies. The main intermodel spread of September SIC is well described by two leading EOFs, which together explain ∼65% of its variance. The first EOF represents an underestimation or overestimation of SIC in the whole Arctic, while the second EOF describes opposite SIC biases in the Atlantic and Pacific sectors. Regression analysis indicates that the two SIC modes are closely related to departures from the multimodel mean of Arctic surface heat fluxes during summer, primarily shortwave and longwave radiation, with incoming Atlantic Water playing a role in the Atlantic sector. Local and global links with summer cloud cover, low-level humidity, upper or lower troposphere temperature/circulation, and oceanic variables are also found. As illustrated for three climate models, the local relationships with the SIC biases are mostly similar in the Arctic across the models but show varying degrees of Atlantic inflow influence. On a global scale, a strong influence of the summer atmospheric circulation on September SIC is suggested for one of the three models, while the atmospheric influence is primarily via thermodynamics in the other two. Clear links to the North Atlantic oceanic circulation are seen in one of the models. 

Abstract The Pico-STRAT Bi Gaz spectrometer provides in situ mixing ratio measurements of water (H₂O) and methane (CH₄) [or carbon dioxide (CO₂)] under balloon. The instrument was flown in the tropical upper troposphere and lower stratosphere in 2019/20 and 2021/22 during the Strateole 2 campaigns for a total of five flights of 20–80 days between 18- and 20-km altitude. In this frame, in situ measurements of water vapor and methane were performed every 4–12 min in the equatorial tropopause layer. On several occasions, water vapor measurements of Pico-STRAT Bi Gaz have been compared with localized measurements from the Fluorescence Lyman-Alpha Stratospheric Hygrometer for Balloon (FLASH-B) Lyman-αhygrometer and vertical profiles of the NOAA Global Monitoring Laboratory (GML) frost point hygrometer over Hilo, Hawaii. Pico-STRAT Bi Gaz measurements agreed with the FLASH-B hygrometer to within 2.2% ± 5.3% between 18.2 and 18.7 km in 2021 and to within 1.3% ± 5.3% near 19 km in December 2019. Pico-STRAT Bi Gaz agreed with NOAA’s frost point hygrometer (FPH) hygrometer to within 1.2% ± 4.1% between 18 and 19 km on four occasions during the two campaigns. These are within both instruments’ uncertainties. Methane measurements from Pico-STRAT Bi Gaz have been compared with in situ measurements from the whole air sampler (WAS) instrument, flown aboard the NASA WB-57 aircraft during the Asian Summer Monsoon Chemical and Climate Impact Project (ACCLIP) 2022 campaign over South Korea, 8 months after the Pico-STRAT Bi Gaz overpass. The relative difference between both instruments is found to be −0.1% ± 0.9% within the altitude range from 17 to 19 km and within the Pico-STRAT measurement uncertainty. 

Abstract Convective gravity waves are important for the forcing of the quasi biennial oscillation (QBO). There is a wave component that is stationary with respect to the convective cells that is triggered by convection acting like a barrier to the background flow (moving mountain mechanism). Waves from this mechanism have only been observed in a few case studies and are not parameterized in climate models. However, the representation of the whole spectrum of gravity waves is crucial for the simulation of the QBO, especially in the lowermost stratosphere (below 50 hPa) where the QBO amplitudes are under‐estimated in current global circulation models. In this study, we present analysis of convective gravity wave observations from superpressure balloons in boreal winter 2019 and 2021, retrieving phase speeds, momentum fluxes, and drag. We also identify waves generated by the moving mountain mechanism using the theory of the Beres scheme as a basis. These waves do not have a specific period, but are of smaller horizontal scale, on average around 300 km, which is similar to the scale of convective systems. Our results show that gravity waves contribute up to 2/3 to the QBO forcing below 50 hPa and waves from the moving mountain mechanism are responsible for up to 10% of this forcing. 

Abstract Terrestrial gamma ray flashes (TGFs) are high‐energy photon bursts that have been linked to short bursts of electromagnetic radiation associated with lightning activity. The most puzzling unexplained aspect of these events is that gamma rays originate from very compact regions of space while the source regions often seem to be optically dim and radio silent when compared to processes in ordinary lightning discharges. In this work, we report a mechanism that allows precise quantitative explanation of these peculiar features of TGFs and their relationships to the observed waveform characteristics of associated radio emissions. The mechanism represents an extension of earlier ideas on feedback processes in growth of relativistic runaway electron avalanches (Dwyer, 2003,https://doi.org/10.1029/2003GL017781), and is based on a recent demonstration of the dominant role of the photoelectric feedback on compact spatial scales (Pasko, Celestin, et al., 2023,https://doi.org/10.1029/2022GL102710). Since discussed events often occur in isolation or precede formation of lightning discharges, the reported findings propose a straightforward solution for the long‐standing problem of lightning initiation. 

Abstract In a recent work, Baladi and Demers constructed a measure of maximal entropy for finite horizon dispersing billiard maps and proved that it is unique, mixing and moreover Bernoulli. We show that this measure enjoys natural probabilistic properties for Hölder continuous observables, such as at least polynomial decay of correlations and the Central Limit Theorem. The results of Baladi and Demers are subject to a condition of sparse recurrence to singularities. We use a similar and slightly stronger condition, and it has a direct effect on our rate of decay of correlations. For billiard tables with bounded complexity (a property conjectured to be generic), we show that the sparse recurrence condition is always satisfied and the correlations decay at a super‐polynomial rate. 

ABSTRACT This study focuses on investigating the conformational structure and zinc(II) affinity of a zinc finger‐like motif (ZFM) peptide with the sequence acetyl‐His₁‐Cys₂‐Gly₃‐Pro₄‐Gly₅‐His₆‐Cys₇, where bold highlights the potential zinc(II) binding sites. Zinc fingers are crucial protein motifs known for their high specificity and affinity for zinc ions. The ZFM peptide's sequence contains the 2His‐2Cys zinc‐binding sites similar to those in natural zinc finger proteins but without the hydrophobic core, making it a valuable model for studying zinc(II)–peptide interactions. Previous research on related peptides showed that collision cross sections and B3LYP modeling predicted that the His‐2Cys‐carboxyl terminus coordination of zinc(II) was more stable than the 2His‐2Cys. Employing a comprehensive approach integrating ion mobility–mass spectrometry and theoretical modeling techniques, various zinc(II) binding modes of the ZFM have been thoroughly compared to ascertain their influence on the competitive threshold collision‐induced dissociation method for measuring the relative gas‐phase Zn(II) affinity of the ZFM peptide. The measured Zn(II) affinity of ZFM is greater than those measured recently for two peptides with similar primary structures, acetyl‐His₁‐Cys₂‐Gly₃‐Pro₄‐Gly₅‐Gly₆‐Cys₇and acetyl‐Asp₁‐His₂‐Gly₃‐Pro₄‐Gly₅‐Gly₆‐Cys₇, indicating the preference for the His₁‐Cys₂‐His₆‐Cys₇side groups for coordinating zinc(II) over the His‐2Cys‐carboxyl terminus or Asp‐His‐Cys‐carboxyl terminus in these related heptapeptides.